H1 is switched off by default, and that is usually right: on most themes the only H1 is the post title, so a contents list built from H1s would have one entry — the page you are already on.
If your content genuinely uses H1 for its sections, tick H1 under Settings → Heading levels. It is worth fixing the content instead if you can, because several H1s on one page is a real accessibility problem independent of this plugin. In the block editor the post's Table of Contents box offers to do it: with two or more H1s it shows Make them H2, which moves the headings under them down with them. Undo, or Ctrl+Z, puts them back, and nothing is saved until you save the post.
Still stuck? Ask the developers who wrote it. We aim to reply within one business day.
